Photo-induced oxidation of [FeII(N4Py)CH3CN] and related complexes

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Photo-induced oxidation of [Fe(II)(N4Py)CH3CN] and related complexes.

The photochemistry of the complexes [Fe(N4Py)(CH(3)CN)](ClO(4))(2) (1), where N4Py is 1,1-di(pyridin-2-yl)-N,N-bis(pyridin-2-ylmethyl)methanamine and [Fe(MeN4Py)(CH(3)CN)](ClO(4))(2) (2), where MeN4Py is 1,1-di(pyridin-2-yl)-N,N-bis(pyridin-2-ylmethyl)ethanamine, in water, dichloromethane and methanol is described. Under UV or visible irradiation both 1 and 2 undergo enhancement of the rate of ...

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ژورنال

عنوان ژورنال: Dalton Transactions

سال: 2012

ISSN: 1477-9226,1477-9234

DOI: 10.1039/c2dt30392b